While it is largely true that 32-bit programs will run fine in the 64-bit version of Windows, this is not univerally true.  Some times the drivers for particular pieces of hardware that interface to a particular program, have not yet been implemented.  My recommendation would be to NOT use the 64-bit version of Windows at this time unless you specifically know that all of your Windows applications are actually supported in the 64-bit version.  The software developer shold be able to give you that information.