I could be wrong, but I'm pretty sure that the bootrom is actually fixed in silicon located directly on the CPU die, not in a separate ROM chip. (Which is partly why I believe the iPhone 3G's bootrom has, to date, not been updated to patch the Pwnage bug in the S5L8900 bootrom DFU code, since it would be a hassle to produce another rev of the CPU simply to fix that hole, and is also why I was really surprised when Apple started manufacturing 3GS phones that patched out 24kpwn in the bootrom. 'cause if they bothered to do it with the 3GS, why not with newly-manufactured 3G phones, too?)
Even if that wasn't the case, the bootrom code is very closely tied to the CPU itself, so, even IF an iPod ROM chip was pin-compatible with the iPhone one, it is extremely doubtful that it would succeed in booting up the device properly.
So, no.
-- Nathan