"The rub is that my High Sierra boot drive is one I want to clone to a bigger SSD. "
There is NO ISSUE here.
There is nothing "additional" or extra you have to do.
CCC will clone from a smaller drive to a larger one -- it doesn't care about size.
You can even clone from a 1tb drive to a 500gb drive -- IF you have used only, say, 300gb.
The drive SIZE is of no importance.
What IS important is HOW MUCH SPACE has been used up on the drive.
Got it?
I think you have gone out of your way to do all of the above "for nothing".
All you really needed to do was connect the smaller drive to the larger one and... clone away.