FoxyKaye said:
I understand not wanting to buy an Airport card given the (insane) cost they're currently selling at, but you can get a router with no wireless capability (which you already have with the Airport Express) for under $50 that will do the job much more efficiently and not consume nearly as much power.
If the appleguy (sorry, dont remember his/her nic) wants the G4 to be available for remote access, the extra power isn't an issue, since it will be running anyway.
But to answer the original question
Yes, with 2 NIC's (network interface cards) in your G4 powermac you can make the following setup:
MODEM -> G4 2NIC -> AIRPORT EXPRESS -> REST OF THE NETWORK
and it will take some fidling (not too much, and with the help of these forums it won't be a problem) but you would have to bear in mind the following
If you are using port forwarding to the REST OF THE NETWORK for whatever reason (it might be you're using a torrent client on your laptop, or a webserver on an other system than the G4) you would have to edit the settings twice, once in your G4 2NIC and once in the AIRPORT EXPRESS, both nodes need to know where the ports need to be forwared too. this can be quite teadious to get the hang of.
What i found helpful in the past is make a drawing first, something like
|MODEM|------|G4|-------|AE|------- |NETWORK|
then write in all the IP adresses where they are static
so when things aren't working, you can analyse step-by-step where the connection doesn't work.
for instance, if in your network you can't surf the web, then first ping the right side of the EA (the wireless IP address). If you get a reply, then the left side (the side which is connected to the G4) and you follow the path of the data until the routing goes bad...
it might seem a bit confusing, but as long as you keep thinking and asking you'd be fine... remember, nothing is too difficult on a mac