Oh man... that's wide open. First off, go dig your camera manual, and find out how to change the metering modes- most cameras these days will have matrix metering, spot metering, and center-weighted metering (some have more, some less). In matrix mode you are essentially letting the camera figure out what the best exposure is (even if you are in full manual mode),and trusting that it gets it right. Center-weighted is more focused- usually about 10-20% of the viewfinder (and obviously in the middle of it), so that you can meter just in that area, and determine what the correct exposure is from that small area. Spot metering is the most precise (~5% of the viewfinder), but you have to be careful where you meter off of.
The idea is that you can get a good reading of what the exposure should be based on the spot you're metering off of. If you're shooting in full program mode, or aperture- or shutter- priority, then you will need to lock the exposure (or remember it and re-enter it in manual mode), when you meter off an area, be it the sky, green trees, whatever. I usually shoot only in manual mode, so for me it's a matter of deciding what the object I want to meter off is, getting the exposure right for that object, then framing the shot and taking it. Sometimes, when I'm shooting in shutter-priority, I meter off something that is medium gray- be it grass, dirt, or even my hand, and then locking the exposure while I take a series of shots. The k10 should have all these options that I've been talking about. It's a matter of learning how to use them now.