You can immediately reset your Mac's system volume to default setting with a restart while resetting PRAM (NVRAM)
Very easy to do that. Restart while holding Command-Option-P and R. You will hear the boot chime sound.
Continue to hold the same 4 keys until you hear the boot chime two more times, then release the keys to allow your Mac to startup normally. You will likely hear a difference between the first and second boot chimes, indicating a reset to default levels.
That PRAM reset will also un-set your startup disk selection, so be sure to go into your System Preferences, then Startup Disk. You will need to unlock that pane by clicking the padlock, before you can set the Startup Disk for your preferred boot drive - usually whatever drive is the internal one.
Anyway, there's your volume reset to defaults.
note for the future: Try to avoid injecting foreign liquids into your iMac. It just doesn't need any form of fertilizer, and you certainly don't want to be spraying Windex directly on your iMac.
Here's what I use to clean the screen. One of those ultrasoft cleaning cloths, lightly sprayed with a vinegar-based glass cleaner (absolutely never ammonia-based). Slightly damp cloth (never wet) will usually clean that glass squeaky clean.
Oh, and try to learn not to touch the glass. Way less need to do much of anything to the screen when you don't ever touch it. (Maybe that's just me
)