It's too small a space to make an independent partition. You might be able to resize your boot partition to include that additional 16MB, but again, it's such a small area that you might not be able to get it to include that. There's a certain margin of error in the Disk Utility GUI for resizing partitions. Strangely enough, maximizing the Disk Utility window changes the scale to allow slightly more fine tuning. But 16MB is a rounding error on a 750GB drive, so it may not help. The Terminal diskutil might work, but to me, it wouldn't be worth playing with my boot drive partition to try to capture it.
FWIW, I looked at my Mac mini's boot volume--a DIY "Fusion" drive--and it shows 679.47 GB capacity, 679.47 GB used, 90 KB available. (It was a 180GB Intel SSD added to the stock 500GB HDD.) So I have a minuscule amount of unallocated space myself.
John