Not entirely. The difference between 24 and 50mm is not only the wieder angle of view but mainly the relative distance and angle between the camera and the elements in the image (nose, eyes, ears, background). With a wider lens you need to get closer to the subject. By that, the angle which you are looking at e.g. the ears is different than if being farther away. You can’t correct that in post.
The other point is the size of nose, eyes, ears etc relative to each other. Let’s say you are extremely close a foot or so from the face, then the ears would be almost twice as far away than the nose, hence the size difference.
Bottom line is that th focal length of the lens is secondary but the distance ecamera and subject is the point. If you use a 24mm lens but take the picture trim the same distance as you would with the 50mm lens, then you can crop in and get the _exact_ same picture as with the 50mm. But you will lose resolution obviously.