Same problem here ... I can manually initiate sleep, but it no longer enters sleep mode after the designated time period. Network wake is disabled. I am not sure if this is something that appeared after the OS X 10.9 Mavericks update?
It may be related to having my RAID-5 external drive connected via USB 3.0 rather than Firewire 800 as I previously had done. I need to do some more testing on this...
-howard