To make your secondary drive bootable:
You will just need to install macOS on your drive. Once that install is complete, it will boot to that drive, to complete the system install.
What version of macOS do you want to install?
What system is installed on your present boot drive? It's a simple matter to boot to your recovery system, and just choose to reinstall macOS, AND choose your mSATA drive as the destination for the system install.
Or, you can use a bootable USB installer to install macOS on your mSATA. This depends on what you need, and what you have now.