Some weird things I find, cannot explain, but this is what I see:
1. Windows installer cannot boot from USB. In theory it should, we can boot the macOS installer from USB no problem, but not Windows Installer. SATA port can boot no problem. If you do not have a windows desktop, what you can do is buy a USB to SATA converter, then make SATA boot drive by mounting it as USB drive. Haven't try DVD, DVD might works.
2. Windows can only be installed on a MBR partition disk.
3. Even after installation, the Windows boot manager cannot be booted. You need to first boot the windows installer, then launch the installed Windows 10 in the installer.
4. Even using the Windows Installer trick in step 3, you still cannot boot your Windows in your NVME disk. I tried.
The best way of installing Windows 10 on Mac Pro 3,1 is:
1. Get a PC and two SATA disks.
2. Make one disk the Windows Installer.
3. Install Windows 10 on the second disk.
4. Plugin both disks to Mac Pro. Boot Windows Installer then select boot from the installed volume. Yes, Windows 10 is robust enough to boot from PC to Mac without reinstallation.
1. Windows installer cannot boot from USB. In theory it should, we can boot the macOS installer from USB no problem, but not Windows Installer. SATA port can boot no problem. If you do not have a windows desktop, what you can do is buy a USB to SATA converter, then make SATA boot drive by mounting it as USB drive. Haven't try DVD, DVD might works.
2. Windows can only be installed on a MBR partition disk.
3. Even after installation, the Windows boot manager cannot be booted. You need to first boot the windows installer, then launch the installed Windows 10 in the installer.
4. Even using the Windows Installer trick in step 3, you still cannot boot your Windows in your NVME disk. I tried.
The best way of installing Windows 10 on Mac Pro 3,1 is:
1. Get a PC and two SATA disks.
2. Make one disk the Windows Installer.
3. Install Windows 10 on the second disk.
4. Plugin both disks to Mac Pro. Boot Windows Installer then select boot from the installed volume. Yes, Windows 10 is robust enough to boot from PC to Mac without reinstallation.