Many Thanks for your answers. I know that I have to press the option key, I just pressed the space bar afterwards to show all boot options, like recovery mode. I have tried to use a usb hub, but the drive still ist not displayed. Then I found an old bootable usb drive with an El Capitan installer (not created with OLCP) on it and this drive is recognized and displayed in the boot picker (with and without a usb hub). Therefore, I assumed that the bootable usb drive not showing up might not have been created properly, so I recreated it. But that didn't solve the problem either. So maybe the usb drive is broken, although it is displayed in finder and accessible. Or could it be that it is not displayed in the OpenCore boot picker because OpenCore ist already running on the Mac.