I only have a single duo card in our MP7,1s. So no idea how you deal with having diffrerent MPX modules in a single mac.
It might not be a supported config.
Learn about the Apple MPX Modules and some of the third-party PCIe cards you can install in your Mac Pro.
support.apple.com
Also 2 duo cards don't seem to connect together with a link anyway, they have a "jumper" to connect internally.
(Anybody own a production double duo to verify what's in there?)