if you have a properly multithreaded app, the upgrade will be significant.
With a single threaded app they will be more or less the same.
3GHz quad core chips are likely on hold at the moment because of a) cost and b) heat. the 3GHz Woodcrests in the Mac Pro are each 15W hotter than the 2.66 and 2.00 versions.
we may see higher clocks down the line, though.