Download DiskWave from here:
It's small in size and free.
Open DiskWave and go to the preferences.
Put a checkmark in "show invisible files".
Close preferences.
The DiskWave window shows you all your volumes and drives in plain English (no ridiculous graphical formats).
Click on any item "on the left".
Now, you'll see what's ON the volume, listed in order of "largest to smallest".
You can easily locate what's eating up your space.