If mold stains have already set in, there are a number of steps to follow. Ideally, the mold stains should be caught as soon as possible, before the organism has had a chance to dig in. Bring the mold stained clothing outside and brush it out, to prevent spores from spreading around your home. Clothing that has been stored in proximity to the mold stained clothing should also be taken out and aired, and wiping down the shelf, drawer, or closet where the clothing was kept with a mild bleach solution will kill any spores floating in that environment.
The next step is to leave the clothing in the sun to dry out, because heat and sunlight kill many varieties of mold. Hang the clothing from a clothes line so that it remains well ventilated and the sunlight falls evenly across most of the garment. Mold stains will likely still remain, because fungus discolors fabric.
Presoak the mold stains in cold water, and then wash hot or warm with detergent. Check the garment before putting it in the dryer to make sure that the mold stains are gone, and wash it again if necessary. Drying the garment in the sun to kill any remaining spores is advised. If the mold stains persist, blot the area with a mild bleach solution, if possible, and launder it again.