Web programming might be an easy place to start, as it is easier to make things which look good (whether they are or aren't) quite quickly, thus giving quick gratification. Programming with C, C++, etc, are not so nice, as it is difficult to make anything but command line applications (but command line applications are quite useful!)
Visual Basic .NET is probably one of the easiest for creating applications with UI, but isn't very powerful. C# is harder to write code for, but otherwise similar to VB.NET.
Java is a relatively good language as it shares characteristics with several other languages, such as PHP, C++, C, C# (in fact, C# and Java are very very similar).
If you are completely new to programming... perhaps Visual Basic .NET would be best, because it allows you to create programs pretty much right out of the box. After you get a feel for programming, I'd suggest either PHP or Java. (Note: PHP is a web programming language)
PHP is a relatively easy language, but it takes a bit to set up, which is why I suggest VB.NET first.