I have just managed to get an eVGA 8800GTS (model number 512-P3-E841-AR) working in Bootcamp with Win XP 32bit on my MacPro1,1. As my Radeon 1900XT is starting to fail I decided to take the risk and hope for nVidia or apple to come out with an efi32 rom for this card at a later time.
Here's what I noticed:
1) you will need to keep your old card (in my case the 1900XT) in one of your pci-e slots and connected to some power source, otherwise your mac wont boot at all. As I didn't have enough power cable at home, this cost me my DVD drive, as I had to pull the power cord that goes to the optical drive cage down to the pci slot area where I used a 4-pin to 6-pin molex connector to power the second card. As I bought the retail version this cable was in the box, YMMV.
2) at first Windows didn't want to use the card at all, even though I had the newest forceware drivers installed. The GTS would show up in the hardware list, but XP wouldn't let me select a resolution and would say that the drivers were for a different version of windows.
3) Windows started to recognize the card first when I put it in Slot 1 and the ati card in slot 2. Now XP still says that when I open the control panel, but I can select the correct resolution now so I guess i'll have to live with that. This is with the newest (beta) forceware drivers and with the 8.4 catalyst drivers installed.
I haven't tried rebooting into OS X yet, so I can't say if the fan will go at max speed then.