I don't find your response on point to my question. Nor are you seemingly recognizing the concern.
My response is a normal and viable solution for your issue.
It is not a simple matter of remembering (or recording) the password.
Of course it is.
If I am understanding the implementation of FileVault and the password connection, it is based on BOTH the password at the time of encryption AND does not change with changes to the Computer (and AppleID password if you have them synced).
So a person would need to have properly document the password of the machine AT THE TIME of encryption.
Someone needs to remember or write down the password that they set.
If I set a Facebook password, I need to remember that. When I go and change my Google password, I need to remember the password that I set for Facebook, because it's not going to change automatically when changing Google's password.
Most passwords aren't interlinked, and if you change one manually, you have to either change the other and remember what the other one was.
I personally am highly organized. I would have this information documented, stored in a safe place, and I would know where to find it if I ever needed it. However, if you support any family/friends, then you will realize that many people (if not most people), simply do not have such structure.
So that's why you write it down, like I said earlier. It's really that simple.
I challenge you...ask 5 random people what their AppleID password is...My bet...
2 of the 5 will ask you "what do you mean my Apple ID password...is that what I use when I buy an app? Wait, I think it is........ Or maybe...... I can't remember if it is a capital letter or not, but try this......".
The other 2 of the 5 will just stare at you blankly and say they don't know if they ever set one up.
1 of the 5 will know it.
Again, like I said earlier, write the password down and store it in a secure place. Now you don't have to worry about any of this.
So I go back to my initial question. Is the FileVault password actually "set and frozen" based on the password in use AT THE TIME of encryption or does it always sync with the users current AppleID password (which can be set/synced as the computer password)?
The FileVault password has nothing to do with the AppleID. You can make it the same password or make it a different one. Just like my IMDB password has nothing to do with my MacRumors password, unless I choose to make it the same password and change both at the same time.
Write your family's passwords down.