Yeah, i use time machine (rotating between both syn boxes) for redundancy, and then use CCC once every two weeks to back up onto a wired drive. Belt and suspenders. I’ve never had to resort to the CCC backup. The speed of the time machine backups doesn’t trouble me to much because it gets in a few backups a day on each box. Whenever time machine does determine That the archive is no good (which it does every 4 or 5 months) on one of the boxes, then I just suck it up and take the 2 days it takes for a full backup. Since it’s normally incremental, it’s not too bad (way slower than it needs to be, but it doesn’t bother me as long as i always have a recent backup in a couple of places.). I actually back up from 5 different macs onto the two synology’s (hint: set up backup accounts on the box and set quotas!), so that probably doesn’t help my performanceI do like the historical look back of Time Machine, though. I use CCC when I need to make a dedicated copy-- I've got a 2013 MP that needs service, so I'll CCC the internal storage to that T7 drive, wipe the drive when I bring the MP in for service, and then restore the CCC copy.
I haven't gone through the hassle of dealing with Synology on this issue, but I suspect the problem is that a TM backup is a huge number of little files which is not well suited to the type of asymmetric array Synology uses. No RAID likes lots of little files, but I have an array of 4 identical disks in my OWC box and it's probably easier to handle with simple striping than it is with whatever games you need to play to spread access, parity and redundancy across drives of different sizes and speeds.