Amazing ! thank you !You need to mount theMacintosh HD - Data
volume, which is separate from the base system volume
OpenDisk Utility
from the main Recovery menu
In the sidebar find the greyed-out volume namedMacintosh HD - Data
Click on that volume and then clickMount
in the tool bar
You will be prompted for a password if FileVault is active
Once mounted the Data volume will be available until you reboot and you can navigate in the Terminal to/Volumes/Macintosh HD - Data/Library/Preferences
to find the files you expect (during a normal boot the Data volume is overlayed on top of the base volume)
I had this issue on 15.2 and it was driving me mad.
so, recovery mode (long press on power), Disk Utility, mounting Data (need password), terminal, remove /Volumes/Data/Library/Preferences/com.apple.networkextension.* , unmount data, reboot, and enjoy.
Many thanks to you @hiapou and @ryanslikesocool for your detailed posts ;-)