I'm assuming you currently have an HDD only unit. The specs for your unit, that are listed in MacTracker.app (available from the App Store) indicate 1 - 6.0 Gbps Serial ATA (SATA), 1 - 8.0 GT/s PCIe x4 which looks like it has a SATA interface for the HDD and a PCIe interface for an SSD. You might want to look at iFixit for more info, although I'm not sure the link below is for your specific model:
HDD: https://www.ifixit.com/Guide/iMac+Intel+27-Inch+Retina+5K+Display+Hard+Drive+Replacement/30522
SSD: https://www.ifixit.com/Guide/iMac+Intel+27-Inch+Retina+5K+Display+SSD+Replacement/30537
Those may not be for your specific model so you would need to verify it, but it states it's for a 27" iMac w/5K retina.
Personally if it was me I'd be looking at getting a Thunderbolt enclosure/cable and put an SSD in that without opening the unit up. That wouldn't be as fast as a PCIe SSD, but it would still be in the vicinity performance wise. You could then couple it with the internal drive to make a Fusion, or you could use the internal drive as a Time Machine backup for the external SSD. The reason I'm saying that is because with your unit being so new I'm assuming it's under warranty and opening the unit up will void the warranty. Of course, just because I'm assuming your unit is under warranty doesn't mean it is.
Hope this was helpful.
HDD: https://www.ifixit.com/Guide/iMac+Intel+27-Inch+Retina+5K+Display+Hard+Drive+Replacement/30522
SSD: https://www.ifixit.com/Guide/iMac+Intel+27-Inch+Retina+5K+Display+SSD+Replacement/30537
Those may not be for your specific model so you would need to verify it, but it states it's for a 27" iMac w/5K retina.
Personally if it was me I'd be looking at getting a Thunderbolt enclosure/cable and put an SSD in that without opening the unit up. That wouldn't be as fast as a PCIe SSD, but it would still be in the vicinity performance wise. You could then couple it with the internal drive to make a Fusion, or you could use the internal drive as a Time Machine backup for the external SSD. The reason I'm saying that is because with your unit being so new I'm assuming it's under warranty and opening the unit up will void the warranty. Of course, just because I'm assuming your unit is under warranty doesn't mean it is.
Hope this was helpful.