If Dali really is a 6W quad, then yes - 6W should be fanless, assuming a decent idle power. I didn't see any 6W intros at CES, though. If they slipped such a processor in without talking about it much, and they can ship in quantity, then they have the whole line covered.
As for the Mac apps porting architectures to ARM vs. iOS apps getting Catalysted, a very well-behaved Mac app should make the architecture jump with just a compiler switch - but MANY Mac apps are not well behaved. Notably, both Office and the big Adobe stuff are massive piles of legacy code.
Office for Mac has long contained a substantial portion of Windows - rather than rewriting Office, Microsoft has included large pieces of Windows so something close to Office for Windows will run on a Mac. I'm not absolutely sure of the latest version, but I think it still does (Office for Mac is (still) several times the size of Office for Windows, which, of course, doesn't need to include Windows).
Office is a sufficient stewpot of code that Microsoft couldn't easily port it to THEIR OWN Surface Pro X - the lousy benchmarks in Office on the Pro X are largely because much of it is emulated. That is "just" Office for Windows - remember that Mac Office is several times the size, and that the difference may very well include tough to port Windows OS code.
Photoshop has historically contained routines written in x86 Assembly Language - if it no longer does, that's relatively recent. Whether or not there's still Assembly in there, there's certainly a mess of languages.
Monsters like that will require a huge amount of hand-coding to port to ARM.
Some little calendar app that lives in the Mac App Store already, and has Mac and iOS versions running off a common code base? Sure, that'll go ARM Mac with a simple compiler switch! Photoshop? Years of hand-tuning!
On the big things where performance matters, that's exactly where Catalyst is easier than porting Mac apps. We'll see Mac apps where there's really no difference between Mac and iOS anyway - but iOS-derived apps instead of the legacy monsters like Office and Photoshop.