According to the review on insanelygreatmac the kit will work with Navigon as far as charging the iPhone and transmitting sound through its speaker. The GPS part won't work.
The review up there is just the first look w/ limited testing. Another review is coming.
What I said was you don't need TomTom to use the kit. Meaning, if you only use TomTom once a month, you can still use the kit daily for calls, iPod, whatever. Other apps do access the GPS.
http://www.youtube.com/watch?v=_Nf-l6_fLXk