I have never seen the mercury playback engine work in CS6 on a Mac running AMD cards. Please explain. It does not work and is the reason Nvidia is preferred at this time and before enterprise takes the hugely expensive CC experiment head on.
Adobe's choice of direction at the time CC came out. Though they've stated that they are planning on moving off of CUDA and going full OpenCL implementation.
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Technically Nvidia cards support OpenCL as well... but they do it poorly. Something along the lines of 1/10th the speed of AMD card OpenCL implementation.