Does
http://www.adt.link have a solution?
I think you want something like the R11SL-TL, R11SL-FL, or R22SL-TL except an x16 version. There's an R33SL (x16 riser) but it doesn't seem to have a TL version. Maybe you can bend one of the R33 risers enough for your needs. the R33SL has some screws that can be removed from the R3S end which might allow extra bending. Or maybe you can ask for a R33SL-TL.
If you can't get a riser that is low profile enough then you may need to raise up the GPU using something like the R33A but that will probably make the HDMI port of the 6950xt unusable unless you modify the Power Mac somehow.
Another problem is that you won't be able to secure raised PCIe cards using the two thumb screw plate of the Mac Pro (does that thing have a name?). You will have to create something for the PCIe cards to attach to or drill some holes or something.
I used 19mm (0.75 inch) standoffs in the example at
#563 but you would need to drill some holes to do that with a Mac Pro.