I'm having the same basic conundrum right now - quad or 8 core? I'll likely be saving up for a few months first, but it's still something I'm uncertain about. I'm leaning towards the 8 core, base mode largely because of the greater RAM expandability.
What I plan to do with it: photo editing (5D mark II RAW processing, 30 meg files), some video work (again the 5DII, 1080p) and multitrack audio recording. I don't really ever plan on doing 3D rendering or CAD/CAM - I'd like to, as making a CNC router for my guitar making seems like it would be interesting and fun, but I simply do not have the time or enough desire to free up the time and money required to get it going. So while I guess a (single, slightly faster) Quad core would be fine in terms of processing power for the next 6 years at least (don't plan many earlier upgrades), I'm not sure the RAM wouldn't become a bottleneck.
Thoughts?
I'm in the exact same boat as you. I also own the 5d Mark II. I about to order the 2.26 Octad with 8GB RAM [I will purchase an extra 4-6 GB from OWC]. Aperture and Final Cut apparently take great advantage of multiple cores. I find the $1500 or so upgrade from 2.26 to 2.66 too much to bear as this gear is just for hobby use and generates no income.