I haven't gotten around to that yet, but I will be. Photoshop is definitely one of those tests I'm hoping should be okay since it relies on AVX-512 functionality. There is no specific AVX-512 setting per se in the Asus BIOS that I have (and one reason why I am eager to test Photoshop functionality on the Asus board), but it is present in the Gigabyte versions.Have you been able to test how the E-Cores (disabled, enabled, with and without hyperthreading) affect Adobe apps, specifically Photoshop?
There's a lot to do still with testing configurations and software. I just managed to install and get Monterey working today. The Z690 systems are currently booting and working both with and without hyperthreading. But if you want to boot into macOS one of either two must be disabled (ie either/or HT or E-cores).
As far as we know it can now/should boot Catalina, Big Sur and Monterey without issues. Thunderbolt 3 also works fully on supported motherboards, but USB 3 settings can be a challenge to set at first.