You seem confused about what the read-only volume is for. No configuration settings are stored there. This link provides a description:These days, most of the configuration settings are stored in the read-only volume and as a normal user, you can't really edit those files...
Apple has really locked down macOS in recent versions and made it more and more difficult, if not impossible, for enthusiasts such as ourselves to dig through the OS and make unauthorized changes....
Signed system volume security
SSV not only helps prevent tampering with any Apple software that’s part of the operating system, it also makes macOS software update more reliable and much safer.
support.apple.com
The basic idea is that files which make up macOS (the stuff distributed to you when you download a macOS installer or macOS updater from Apple) should not be allowed to be altered by attackers trying to hack your computer. By separating just those system files out into a read-only volume, Apple made that kind of tampering harder. In macOS 11, they extended the concept further by using cryptographic signature checking to "seal" the read-only volume. This lets them detect any tampering done to the system volume while the computer was booted into an alternate OS which doesn't respect the read-only setting on the system volume.
Configuration is not stored on the system volume. If it was, it could not be altered except during a macOS install or update, and therefore it wouldn't be configuration.
Like @leman says, you can still mess with anything you like. Apple's design puts you, the user, in charge of whether you want your system files to be tamperable or not. If you want less protection, you merely reboot into RecoveryOS and change the system security settings there. (They designed this to require the reboot into Recovery so there's no way to script it, which would be handy for an attacker. It also reduces the chances that an attacker can "social engineer" a naive user into downgrading security.)