For those interested in gaming via bootcamp with the nMP I may have some slightly disappointing news.
From my tests with a couple of games (12 core, D700), it does not appear that you can simply turn on CF in the driver and have all games benefit automatically. I just got the machine today and still plan to test a bunch of games, but with a couple I've tried so far I'm getting identical FPS with and without Crossfire enabled in the FirePro control center, which would indicate its not working in those games at least. Further, the FPS I'm getting (observed via Fraps) isn't spectacular, it's very close to a PC gaming rig I built a couple years back which is rocking a single GTX 670, leading further evidence that the results I'm getting are from a single D700.
I've seen other benchmarks though (diablo, wow) where people are clearly getting different results with/without CF enabled, so it may depend on the game. Next on my list is BF4 and Skyrim.
Edit: Tried it out, and BF4 is obviously attempting to use both cards - there's a clear FPS difference with it enabled vs. not when running through an in-engine cinematic (a fairly controlled environment), but it also doesn't run particularly great either way. Performance is a little choppy/eratic under crossfire, and nowhere near double performance. This doesn't surprise me as BF4 on my PC has had a number of issues that require bleeding edge drivers on consumer cards, custom tailored for the game. I'll try more games tomorrow.