Sounds like there was already something wrong with the heat dissipation before the mod. I wouldn't use pads much thicker than 0.5mm, otherwise the pad would act like an insulator than a conductor.
And you don't have any background tasks that are chewing up the CPU?
Not really. I first started noticing the high temps a few months ago, when I installed Windows 10 on Bootcamp, ran HWiNFO and saw the CPU between 90C and 100C with normal CPU usage -- browsing the web, watching videos, no intensive or CPU-chewing tasks. And idling at around 70C.
Then I checked the temps on MacOS and they were the same. I already did a clean MacOS install, every system update and no other sofware. Temps were still around 70C when idling and 90-100C when using Safari, for example.
That's when I guessed it should be hardware-related and found this thread. But now, after no change with the 0.5mm pads and thicker pads possibly complicating things further, I don't know what to do. Maybe replacing the heatsink?