Curious if you put a fan blowing out from the back vent would it provide better cooling?
No. The best move it is to put heat the the edge of the system and then blow the heat straight out of the enclosure. The fan being on the other edge of the enclosure means your heat source would have to be more inside the enclosure than the fan.
What Apple has is two heat pipes that move the heat to two radiators just inside the exit vent and blow the air over that radiator ( heating the air) and then out of the box. Far better to have the fan upstream of that. The pipes will radiate a bit before get to the edge but CPU and GPU are sizable so "everything" can't be under the vent.
As long as willing to make lots more noise (more air mass moved per square inch per second. ) what is there should scale up. And if the connection feeding the heat pipes are more efficient ( more heat easily moves to the heat pipe ) , then heat will end up on the enclosure edge.
iMac Pro has a larger vent. The CPU and GPU radiators can be displaced a bit from each other ( each getting "half" of the larger exit vent). The two fans pump twice as much air. Can more move air at a slower speed through a bigger hole ( offset slower speed with more stuff. ).
A big fan at the edge is only more effective if have left most of the heat somewhat randomly scatter the internals and now have to try to capture and blow it out of the box. That is closer to cleaning up the mess after the fact. Have already let the heat wander off and impact other internal parts.
Thinking the hot air is no longer directly benefiting from the fan which is before the heat sink.
The fan's primary job isn't to "cool" the air. It is the
move the air. Hot air is just plain bad. Want to get rid of it as quickly as possible. How the hot air is cooled by something outside the system is something else's "problem'. Inside the enclosure just want to get rid of it.
The fixed conduit for the fan's direct exhaust to the radiator and exit vent also are all about movement, not immediate cooling. Farther away doesn't make much of material difference to air speed if don't let other stuff get in the away or let the air wander off path.