cMP firmware will/does not load legacy bootcode on USB connected drives and only sees USB drives as bootable if they are set up for UEFI boot (including Apple's extension of the spec).
This is similar to what will happen on a PC when the firmware (aka BIOS) is set to UEFI mode as cMP firmware presumably is. The difference is that you have access to the BIOS settings on a PC to change the boot type setting; unlike on a cMP.
If you refer back to the guide here, you will note it specifically says to use a disk connected to a SATA port. So the suggestion is to keep your spare and connect it to a SATA port if/when you need it.
Alternatively, you could try to find a way to access the hidden BIOS interface on your unit and fiddle with the settings there. Some have taken a brief look but I don't think anyone has ventured much into possibilities. Some hardcore guys such as
@dosdude1 might have, but he appears focused on laptops and other disposables. Don't think he plays with cMP.