Every USB 3.x hub contains at least two USB hubs - one for USB 2.0 and another for USB 3.x.(Inland has been returned)
Vantec UGT-PC371AC is seen as (1b21:1242)
The StarTech HB31C3A1CS [chip spec is Realtek - RTS5423] is seen as (14b0:012d)
The Vantec NextStar 3.1 NST-37OA31-BK enclosure is only seen as (174c:1351) when connected directly to the pci-e card (same as the Factory Easystore ext.).
The Vantec NST-205C3-SG nvme does not connect through the Hub, and only directly attached to the UGT-PC371AC.
Only BS(OC) on the MP; I have not tried it on my MBP (BS(Native)) . . . will try that later, to rule-out OC
Strange that some thumb drives are visible when plugged into the ST hub (various 2.0), and others are not (a Memorex 3.1, for one). I get no connect with any external enclosure I have.
For example, the CalDigit Element Hub contains 4 hubs:
USB 2.0: 2188:0034 -> 2188:0031
USB 3.x: 8087:0b40 -> 2188:0032
Two hubs for USB 2.0, 4 ports for the first, 8 ports for the second, with the 2nd hub connected to the first. The first hub is for the 3 USB-C ports. The second hub is for the 4 USB-A ports and a billboard device 2188:0035 with 3 unused ports.
Two hubs for USB 3.x, 4 ports for the first, 5 ports for the second, with the 2nd hub connected to the first. The first hub is for the 3 USB-C ports. The second hub is the for 4 USB-A ports with 1 unused port.
(Have to use ioreg or IORegistryExplorer.app to see how many ports each bus and hub has - The Thunderbolt tab in System Information.app is more informative than the USB tab because it shows ports even if nothing is connected to them)
I can't seem to get USB 2.0 devices to work from the USB-A ports when the Element Hub is connected to the ASM1142 of the Mac Pro 2008 (running Catalina), but they do work from the USB-C ports. USB 3.x devices work from USB-C and USB-A ports.
So I tried the hub with various ports of the Mac mini 2018 (running Monterey):
Thunderbolt port: all works including USB 2.0 from the USB-A ports
W5700 USB-C port: same problem as MacPro3,1 ASM1142.
ASM1142 in Thunderbolt enclosure (Sunix UPD2018): same problem as MacPro3,1 ASM1142.
ASM3242 in Thunderbolt enclosure (StarTech PEXUSB321C): same problem as MacPro3,1 ASM1142.