It is possible to start most (if not
any) x64 operating system directly on the Mac. Not advisable, though, if the system you are trying to run is Windows, as it will wreck your NVRAM.
I don't know if you have a native boot screen capable GPU, but the whole ordeal is not that complicated, so:
- start with copying your whole Open Core EFI folder from m2 SSD to the desktop
- if you have a
native boot screen capable card, insert your Windows USB installer, mount it's EFI partition, copy the EFI folder from the desktop to USB EFI partition, shutdown, remove the m2 SSD, boot from USB (hold option between chime and Apple logo, select USB's EFI on boot screen), proceed with Windows installation.
- if you don't have such card or don't want to mess with your Windows USB installer, follow the steps to create an
OpenCore rescue CD with your existing OpenCore setup as the basis. Once it's done, shutdown, remove the m2 SSD, insert the Windows USB installer and boot from CD (hold C between chime and Apple logo). OpenCore will start from the CD and allow you to proceed with Windows installation.
(remember - Windows does restarts during install, every time it happens you need to make sure it restarts using OpenCore - so either after any restart you need to select the USB EFI as the boot source and once Open Core boot picker is visible you need to select the "Windows" disk, or use the CD and proceed accordingly)
No matter which way you go, once you're done, reinstall the m2 SSD,
again start from an external OpenCore EFI (USB or CD), using OpenCore boot to MacOS. Mount your EFI partition, mount the Windows EFI partition, move the "Microsoft" folder from Windows EFI to your MacOS boot EFI, re-bless the MacOS by selecting "restart" from System Preferences. Now you should see two options on OC boot - MacOS and Windows.