Always install macOS with the GPU you want to use by using OCLP.I bought a used ASUS AMD Radeon RX 6600 XT, patched it with your method. It runs on a MacPro 3,1 a 4,1>5,1 and a 5,1. However, the card is not registering correctly and has therefore no acceleration.
I did an OpenCore 0.6.1 clean install of Monterey 12.6.3 on all three MacPros with an ATI Radeon HD 5770 and then switched to the RX 6600 XT.
My Radeon RX 580 works perfectly fine under this conditions.
I have no idea what is missing with the RX 6600 XT, maybe I will patch the card one more time.
5770 isn't a supported card, OCLP will patch the OS for you, which somehow may cause issue to other natively supported GPU.
This isn't Syncretic patch's fault.
Also, I believe you mean OCLP 0.6.1 but not OpenCore 0.6.1. Otherwise, the OC version is way too old.
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