Hello SoulCreation,
Welcome.
I have not tried Pikify with that combination. However, you should be okay to “build” the modified installer from your Mac Mini onto the external drive.
El Capitan, Sierra, and High Sierra all implement SIP (system integrity protection). This means that your Mac Mini cannot set the “next boot” volume programmatically because it is running High Sierra with SIP enabled. Correctly signed helper applications might be able to do this, but the Pikify app is not signed for various reasons.
Please understand that the whole Pike-modified system is designed to boot the Mac Pro. It is probable that the modifications are not compatible with your Mac Mini. Therefore it may not boot the Mac Mini.
My recommendation is to re-fit the drive into your MacPro.
At boot, when you hear the chime, hold down the Alt key.
You should be presented with the boot selector screen.
You should see your hard disk.
Select this to boot.
Cross your fingers, hold your breath...
Hopefully it will boot into the installer...
Alternatively, you can keep the HDD attached to your MacMini, run the “Install OS X El Capitan” app directly on the Mac Mini (no need for Pikify, or any other modifications at this stage). I think it will launch (it might not launch or it might not allow you to continue because your Mac Mini is at a higher release of the OS, but if it does, then...) then simply choose to install on the external HDD.
You must then replace the two boot.efi files on the external drive manually.
Optionally, replace the boot.efi file on the Recovery HD partition of the external HDD too (you will need to search for instructions of how to mount the Recovery HD partition).
Once you have done that, re-fit the external HDD to your MacPro.
Thank you for your suggestion.
Last night while sleeping I dont know how I thought of this:
Clone MacMini High Sierra then dismount the external its clone too --> refit MacMini with ElCapitan [as I have a usb fresh install El Capitan unmod]. If this works then I can do the Pikify onto another external drive for the MacPro1,1 and get that up and running.
What do you think? A bit of a hassel but it might work as a last ditch effort if I cannot install from MacMini to External HD. It said unable on first attempt but I read somewhere last night on google search, something about enter my appleID to allow. I will research that some more before I attempt, otherwise I might borrow a friends computer for an hour to get it on my external. I am just trying not to bother friends.
I will try the drive in the MacPro 1,1 prior, just in case it works.
I am hoping for the just in case to work. Awaiting a new gpu: ati radeon 5770 to arrive, I bought one that is apple compatible so hoping it works out of the box.
Another question if you don't mind to answer: is it better to do clone for back up vs using time machine?
I have always cloned before each new download and save them for just in case moments but I never have used time machine... not sure if its worth it or if I just need to expose myself by getting to know it better.