What about with battery removed? Pin 3 seems odd. That is just a simple resistor divider to generate 4V from the 16V coming in. But your pin 1 is at 12V which is also a bit odd. Usually it drifts up to 16V to completely turn off the input FET. Let me know what the readings are without the battery plugged in and just the magsafe.
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That pin 2 CHGR_DCIN is weird. You have 4.7V on pin 3 so that means the resistor divider is getting >16V. But then pin 2 should be getting that same 16V. Check R7005 the 20ohm resistor near pin 2. It may have gone open circuit. Measure resistance with all power removed.
Pin 1/2 16.5v
Pin 3 24.7mv
pin 14 0v
Pin 19/20 5v
everything else basically 0v or really small mv reading